土木工程学报  2019, Vol. 52 Issue (S2): 14-22    
  结构工程 本期目录 | 过刊浏览 | 高级检索 |
NaCl溶液中不同含水率高岭土的变形特性
于海浩1  孙德安2  于明波3  蒋仕清3
1.桂林理工大学广西岩土力学重点实验室,广西桂林 541004;2.上海大学,上海200444;
3.中国建材集团建材桂林地质工程勘察院有限公司,广西桂林541004
Deformation characteristics of kaolinite clay with different initial water #br# contents in NaCl solution
Yu HaihaoSun DeanYu Mingbo3  Jiang Shiqing3
1. Laboratory of Geomechnics and Geotechnical Engineering, Guilin University of Technology, Guilin 541004, China;
2. Shanghai University, Shanghai 200444, China; 3. Guilin Institute of Geological Engineering Investigation,
China National Building Material Group, Guilin 541004, China
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摘要 土试样的初始结构和孔隙溶液的化学性质强烈影响其力学行为。为探究不同初始含水率以及不同浓度NaCl溶液对高岭土的体积变形的影响,进行了一系列膨胀压缩试验。不同初始含水率试样被不同浓度NaCl溶液浸入饱和,待变形稳定后再进行压缩试验。对膨胀稳定后的试样进行核磁共振试验发现,膨胀后的高岭土试样中孔隙水有两种赋存状态,一种为在颗粒表面受到扩散双电层影响的吸附水,另一种为存在于孔隙中的水。当试样浸入NaCl溶液后,饱和度增加,有效应力降低,试样发生膨胀。由于扩散双电层的影响,使得土颗粒之间形成广义渗透压,在同样条件下,随着NaCl溶液浓度的增加,广义渗透压力降低,考虑化学作用的颗粒间的有效应力增加,膨胀率随之降低。在相同压实功下,随着初始含水率的增加,由于试样颗粒排列趋向定向,小于0.01μm的孔径增加很多,而小于0.01μm部分孔径很难压缩。
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于海浩 孙德安 于明波 蒋仕清
关键词 高岭土初始含水率NaCl溶液膨胀压缩    
Abstract:The mechanical behavior of clays is strongly affected by the pore structure state and pore fluid composition. The aim of this paper is to investigate the effects of initial water content and NaCl solution on the volume change behavior of kaolinite clay. In this study, numbers of kaolin specimens with different initial water contents were exposed to different concentrations of NaCl solution in the wetting test. And then these specimens were compressed in oedometer. The results of nuclear magnetic resonance (NMR) tests on the specimens after wetting tests showed that the pore water of the swelled specimens existed in two ways. One way is the adsorbed water on the surface of particles that was affected by the diffuse double layers. After exposing to NaCl solution, the effective stresses decreases with increasing in the degree of saturation. Because of the diffuse double layers on the particle surface, there was generalized-osmotic pressure in the specimens. The generalized-osmotic pressure decreases with increasing the concentration of NaCl solution, which results in a decrease in swelling strain. At the same compactive effort, the soil fabric becomes increasingly oriented with an increase in water content which it results the pore-size less than 0.01μm increasing. The pore-size less than 0.01μm is hard to be compressed.
Key wordskaolinite clay    initial water content    NaCl solution    swelling    compression
    
引用本文:   
于海浩 孙德安 于明波 蒋仕清. NaCl溶液中不同含水率高岭土的变形特性[J]. 土木工程学报, 2019, 52(S2): 14-22.
Yu Haihao Sun Dean Yu Mingbo Jiang Shiqing. Deformation characteristics of kaolinite clay with different initial water #br# contents in NaCl solution. 土木工程学报, 2019, 52(S2): 14-22.
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